They are the second nation to qualify for the tournament after Canada booked their place earlier this month.
Manu Samoa will play in Pool D against champions South Africa, Wales and Fiji.
Samoa won 188-19 on aggregate over two matches against Papua New Guinea, having won 115-7 at Apia Park a week ago.
Wing Mikaele Pesamino opened the scoring with the first of his three tries after only four minutes at the Lloyd Robson stadium on Saturday.
Five more unanswered first-half tries by Eliota Fuimaono-Sapolu, Andrew Williams (2), Semo Sititi and a second for Pesamino, allied with four Titi Esau conversions, saw the visitors take a 38-0 half-time lead.
Roland Namo claimed one back for the Pupuks in the second-half before further scores from Fuimaono-Sapolu, Afa Aiono, Meki Magele, Pesamino and Gavin Williams.
Jack Maraha scored a late consolation try for the home side.
Eliota will now fly back to the UK to link up with his new Gloucester Rugby team mates in time for the 2009-10 season.
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